Piatt and Fleming have stained fats and oils with Sudan HI, a red dye
soluble in fats but not soluble in water, and examined the baked products
and the batter, in this case cookies, under the microscope. They find the
fat to be in thin layers between the starch granules when the material is
mounted dry. In some instances the fat completely surrounds the starch
granules; in others the granules touch with no fat layer between them.
These layers of fat, which physically separate different parts of the dough
and prevent them from coming together in a solid mass, vary in thickness
in different sections of the dough. To have the best shortening effect a
fat must adhere to the flour particles and not be squeezed out by pressure.
They give the following order for the shortening power of different fats,
lard having the greatest shortening power.
Lard
Lard compound
Cottonseed oil
Butter
Coconut oil
Vaseline
> Purified petroleum oils, as Nujol
568 FATS AND OILS
For these differences In shortening power, Piatt and Fleming have sug-
gested that the following factors have minor or major effect: viscosity,
surface tension of oil, the melting point of the fat, and orientation of the
molecule due to double bonds of the fatty acid chains of the glycerides.
The following is a short summary of their article.
Viscosity gives a fat the power of spreading easily in the dough ; a more
viscous fat will run out of the dough less readily in baking, but it is of
relatively little importance in shortening power, as shown by the fact that
some of the petroleum products were as viscid as lard but gave less shorten-
ing power.
A melting point close to that of lard seems desirable, yet this factor
alone is not a satisfactory explanation in all cases, as coconut oils may be
prepared having the same melting point as butter but less shortening power.
Plasticity gives a fat the ability to spread easily, which is beneficial ; but
the fact that the oils having no plasticity give greater shortening power
than butter shows that plasticity is only one of the important factors.
Owing to orientation of molecules, fats containing unsaturated glycerides
cover a greater surface area than those with saturated glycerides. The
shortening power of fats tested, with the exception of lard and lard com-
pound, was in the same order as the percentage of unsaturated glycerides
contained by the fats.
The author has found that an oil is partially or wholly emulsified as
an oil-in-water emulsion in uncooked cake batter. However, the cake batter
contained milk and egg, whereas the cooky batter of Piatt and Fleming
did not contain milk. In cake batters an unmelted fat is distributed in
sheets, layers, or films of different thicknesses between the starch granules,
and around the air bubbles and sugar crystals. Whether the oil remains
emulsified during baking of a cake batter might have some effect on the
finished product, but the distribution of the oil or fat when the batter
or dough is being mixed undoubtedly affects the tenderness, for this is the
period w^hen the gluten is being developed.
Page 453
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Piatt and Fleming have stained fats and oils with Sudan HI, a red dye
soluble in fats but not soluble in water, and examined the baked products
and the batter, in this case cookies, under the microscope. They find the
fat to be in thin layers between the starch granules when the material is
mounted dry. In some instances the fat completely surrounds the starch
granules; in others the granules touch with no fat layer between them.
These layers of fat, which physically separate different parts of the dough
and prevent them from coming together in a solid mass, vary in thickness
in different sections of the dough. To have the best shortening effect a
fat must adhere to the flour particles and not be squeezed out by pressure.
They give the following order for the shortening power of different fats,
lard having the greatest shortening power.
Lard
Lard compound
Cottonseed oil
Butter
Coconut oil
Vaseline
> Purified petroleum oils, as Nujol
568 FATS AND OILS
For these differences In shortening power, Piatt and Fleming have sug-
gested that the following factors have minor or major effect: viscosity,
surface tension of oil, the melting point of the fat, and orientation of the
molecule due to double bonds of the fatty acid chains of the glycerides.
The following is a short summary of their article.
Viscosity gives a fat the power of spreading easily in the dough ; a more
viscous fat will run out of the dough less readily in baking, but it is of
relatively little importance in shortening power, as shown by the fact that
some of the petroleum products were as viscid as lard but gave less shorten-
ing power.
A melting point close to that of lard seems desirable, yet this factor
alone is not a satisfactory explanation in all cases, as coconut oils may be
prepared having the same melting point as butter but less shortening power.
Plasticity gives a fat the ability to spread easily, which is beneficial ; but
the fact that the oils having no plasticity give greater shortening power
than butter shows that plasticity is only one of the important factors.
Owing to orientation of molecules, fats containing unsaturated glycerides
cover a greater surface area than those with saturated glycerides. The
shortening power of fats tested, with the exception of lard and lard com-
pound, was in the same order as the percentage of unsaturated glycerides
contained by the fats.
The author has found that an oil is partially or wholly emulsified as
an oil-in-water emulsion in uncooked cake batter. However, the cake batter
contained milk and egg, whereas the cooky batter of Piatt and Fleming
did not contain milk. In cake batters an unmelted fat is distributed in
sheets, layers, or films of different thicknesses between the starch granules,
and around the air bubbles and sugar crystals. Whether the oil remains
emulsified during baking of a cake batter might have some effect on the
finished product, but the distribution of the oil or fat when the batter
or dough is being mixed undoubtedly affects the tenderness, for this is the
period w^hen the gluten is being developed.