Sheppard and Hudson have reported a new form of gelatin. It is called
pressed foam gelatin. It is said to absorb water rapidly and to dissolve
rapidly and it is not excessively bulky.
Hydrolysis of Collagen
Temperature. When collagen is heated with water, gelatin is formed.
Bogue states that this occurs at 80° to 90°C. or at higher temperatures. The
reaction occurs more rapidly at higher temperatures, but at these tempera-
tures more of the gelatin is hydrolyzed to proteoses, peptones, or amino
acids. When meat is cooked in hot water the collagen of the connective
tissue is converted to gelatin. The gelatin is soluble in the hot water, and
as it is dissolved the muscle fibers are separated and fall apart. At tem-
peratures below the boiling point of water a longer time is required to
hydrolyze the collagen to gelatin.
Acids. The addition of a dilute acid hastens the hydrolysis of collagen,
but this also increases the hydrolysis of the gelatin to peptones and amino
acids. The latter products do not form gels, so that, in the manufacture
of gelatin, it is not desirable for the gelatin to contain very much of these
products. Softening of connective tissue in cooking meat is brought
about in a shorter time by the addition of a small amount of acid.
Tomatoes added to a stew will accomplish this purpose. Sometimes vinegar
is used.
f
180 GELATIN
Properties of Gelatin
Gelatin Is characterized by forming a solution in water at high tem-
peratures and, with high enough concentration, a gel at low temperatures.
The dry gelatin has a slightly yellow cast and contains from 10 to 18
per cent of moisture. It swells when put in cold water, the degree of
swelling being modified by acids, alkalies, or salts. It dissolves at about
35 °C., and it gels at low temperatures, the exact gelation temperature
depending upon the concentration and time of standing.
Swelling and Solution
The extent to which gelatin swells in water is modified by the surface
area, its initial /»H, the presence of or addition of acids, alkalies, and in-
organic salts, and its previous history. Bogue states that gelatin tends to
absorb water equal to the amount of water it held at the last warming,
but not very much over this. Thus the degree of swelling Is modified by
the previous history of the sample. This would include treatment during
manufacture.
Ease o£ hydration of gelatins. The pulverized gelatin swells most
rapidly, for It Is finely divided, hence has a greater surface area. Granu-
lated gelatin absorbs water quickly, not so rapidly as pulverized, but rapidly
enough so that It Is easily used in the home. Sheet gelatin may be thin or
rather thick. The thin form Is easily hydrated, but the thick does not
hydrate so readily, and therefore requires longer soaking in cold water or
a longer period of heating to dissolve. In preparing gelatin dishes the gela-
tin Is usually allowed to soak In a small amount of cold water. During
this soaking it swells. Bogue suggests that this swelling, by the formation
of capillary spaces In the Interior of the gelatin particles. Increases the
surface of the gelatin.
Page 145
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Sheppard and Hudson have reported a new form of gelatin. It is called
pressed foam gelatin. It is said to absorb water rapidly and to dissolve
rapidly and it is not excessively bulky.
Hydrolysis of Collagen
Temperature. When collagen is heated with water, gelatin is formed.
Bogue states that this occurs at 80° to 90°C. or at higher temperatures. The
reaction occurs more rapidly at higher temperatures, but at these tempera-
tures more of the gelatin is hydrolyzed to proteoses, peptones, or amino
acids. When meat is cooked in hot water the collagen of the connective
tissue is converted to gelatin. The gelatin is soluble in the hot water, and
as it is dissolved the muscle fibers are separated and fall apart. At tem-
peratures below the boiling point of water a longer time is required to
hydrolyze the collagen to gelatin.
Acids. The addition of a dilute acid hastens the hydrolysis of collagen,
but this also increases the hydrolysis of the gelatin to peptones and amino
acids. The latter products do not form gels, so that, in the manufacture
of gelatin, it is not desirable for the gelatin to contain very much of these
products. Softening of connective tissue in cooking meat is brought
about in a shorter time by the addition of a small amount of acid.
Tomatoes added to a stew will accomplish this purpose. Sometimes vinegar
is used.
f
180 GELATIN
Properties of Gelatin
Gelatin Is characterized by forming a solution in water at high tem-
peratures and, with high enough concentration, a gel at low temperatures.
The dry gelatin has a slightly yellow cast and contains from 10 to 18
per cent of moisture. It swells when put in cold water, the degree of
swelling being modified by acids, alkalies, or salts. It dissolves at about
35 °C., and it gels at low temperatures, the exact gelation temperature
depending upon the concentration and time of standing.
Swelling and Solution
The extent to which gelatin swells in water is modified by the surface
area, its initial /»H, the presence of or addition of acids, alkalies, and in-
organic salts, and its previous history. Bogue states that gelatin tends to
absorb water equal to the amount of water it held at the last warming,
but not very much over this. Thus the degree of swelling Is modified by
the previous history of the sample. This would include treatment during
manufacture.
Ease o£ hydration of gelatins. The pulverized gelatin swells most
rapidly, for It Is finely divided, hence has a greater surface area. Granu-
lated gelatin absorbs water quickly, not so rapidly as pulverized, but rapidly
enough so that It Is easily used in the home. Sheet gelatin may be thin or
rather thick. The thin form Is easily hydrated, but the thick does not
hydrate so readily, and therefore requires longer soaking in cold water or
a longer period of heating to dissolve. In preparing gelatin dishes the gela-
tin Is usually allowed to soak In a small amount of cold water. During
this soaking it swells. Bogue suggests that this swelling, by the formation
of capillary spaces In the Interior of the gelatin particles. Increases the
surface of the gelatin.